The Journal of Organic Chemistry

Fluoronitro aliphatics. II. Fluorodinitromethyl compounds. Synthetic approaches and general properties

MJ Kamlet, HG Adolph

文献索引：Kamlet,M.J.; Adolph,H.G. Journal of Organic Chemistry, 1968 , vol. 33, p. 3073 - 3080

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被引用次数: 74

摘要

Preparative procedures are described for a new class of compounds containing the FC (N02) z-moiety. Three general synthesis methods are most useful in this series:(1) fluorination of 1, l-dinitro carbanion salts withperchloryl fluoride;(2) aqueous fluorination of 1, l-dinitro carbanions (the Grakauskas reaction);(3) reactions of fluorotrinitromethane with a variety of nucleophiles.