Air oxygenation chemistry of 4-TBC catalyzed by chloro bridged dinuclear copper (II) complexes of pyrazole based tridentate ligands: synthesis, structure, magnetic …

…, A Girard, C Mathonière, M Nethaji, R Clérac…

文献索引：Banerjee, Ishita; Samanta, Pabitra Narayan; Das, Kalyan Kumar; Ababei, Rodica; Kalisz, Marguerite; Girard, Adrien; Mathoniere, Corine; Nethaji; Clerac, Rodolphe; Ali, Mahammad Dalton Transactions, 2013 , vol. 42, # 5 p. 1879 - 1892

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被引用次数: 9

摘要

Four dinuclear bis (μ-Cl) bridged copper (II) complexes,[Cu2 (μ-Cl) 2 (LX) 2](ClO4) 2 (LX= N, N-bis [(3, 5-dimethylpyrazole-1-yl)-methyl] benzylamine with X= H (1), OMe (2), Me (3) and Cl (4)), have been synthesized and characterized by the single crystal X-ray diffraction method. In these complexes, each copper (II) center is penta-coordinated with square- pyramidal geometry. In addition to the tridentate LX ligand, a chloride ion occupies the last ...