Thermal decomposition of some perfluoro-and polyfluorodiacyl peroxides

C Zhao, R Zhou, H Pan, X Jin, Y Qu…

文献索引：Chengxue, Zhao; Renmo, Zhou; Heqi, Pan; Xiangshan, Jin; Yangling, Qu; et al. Journal of Organic Chemistry, 1982 , vol. 47, # 11 p. 2009 - 2013

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被引用次数: 77

摘要

Seven polyfluoroacyl peroxides were synthesized, some of them by a new procedure involving the direct interaction of an acyl fluoride with hydrogen peroxide. In the temperature range of 20-40" C, all these peroxides undergo first-order decomposition in dilute 1, 1, 2- trichloro-1, 2, 2-trifluoroethane (Freon-113) solutions (50.02 M.). The major decomposition products were separated and characterized as the coupling products of the corresponding ...