Synthetic communications

CAN-mediated oxidative free radical reactions in an ionic liquid

G Bar, F Bini, AF Parsons

文献索引：Bar, Gregory; Bini, Fabien; Parsons, Andrew F. Synthetic Communications, 2003 , vol. 33, # 2 p. 213 - 222

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被引用次数: 30

摘要

Abstract Cerium (IV) ammonium nitrate-mediated oxidative radical reactions are carried out in the presence of ionic liquids, including 1-butyl-3-methylimidazolium tetrafluoroborate, for the first time. The presence of the ionic liquid not only increases the rate and yield of reactions in dichloromethane but also extends the range of 1, 3-dicarbonyl precursors, which can be utilized in these carbon–carbon bond-forming reactions.