A study of factors affecting enantioselectivity in the oxidation of aryl benzyl sulfides in the presence of chiral titanium catalysts
…, G Fracchiolla, F Naso, C Cardellicchio
文献索引：Capozzi, Maria Annunziata M.; Centrone, Caterina; Fracchiolla, Giuseppe; Naso, Francesco; Cardellicchio, Cosimo European Journal of Organic Chemistry, 2011 , # 23 p. 4327 - 4334
Abstract A series of experiments was performed to test a theoretical model that we have recently proposed to explain the highly enantioselective oxidation of aryl benzyl sulfides with tert-butyl hydroperoxide in the presence of a complex between titanium and (S, S)-or (R, R)- hydrobenzoin. The studied variations involved the sulfides, the ligands, and the order of addition of reactants. The reaction path predicted by our model was confirmed in every ...
