Tetrahedron Letters

First example of an atropselective dehydro-Diels–Alder (ADDA) reaction

P Wessig, C Pick, U Schilde

文献索引：Wessig, Pablo; Pick, Charlotte; Schilde, Uwe Tetrahedron Letters, 2011 , vol. 52, # 32 p. 4221 - 4223

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被引用次数: 7

摘要

Abstract A new concept of a stereoselective synthesis of axially chiral biaryls, formed in the course of the dehydro-Diels–Alder (DDA) reaction, has been disclosed. It is based on asymmetric induction of the newly formed chirality axis by a chirality center, which is present in the two synthesized DDA reactants. Depending on the different length of the linkers joining the alkyne moieties the DDA reaction may be triggered photochemically or ...