Structure sensitivity for ethene dimerization, homologation and metathesis on SiO 2-supported catalysts derived from Mo (NMe 2) 4 and Mo 2 (NMe 2) 6

Q Zhuang, K Tanaka, M Ichikawa

文献索引：Zhuang, Quan; Tanaka, Katsumi; Ichikawa, Masaru Journal of the Chemical Society, Chemical Communications, 1990 , # 21 p. 1477 - 1478

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被引用次数: 5

摘要

Organometallic compounds, including metal clusters, grafted on the surface of supports have been widely used as catalyst precursors to provide a rational approach for the preparation of tailored metal catalysts.1 It is known that ethene metathesis proceeds on both homogeneous and heterogeneous Mo catalysts,2 while ethene homologation takes place on hetero- geneous Mo catalysts.3 Ethene dimerization has only been reported to occur when monomer Mo ...