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The reaction of trialkylvinylborate with carbon dioxide. A new method for the preparation of β-hydroxycarboxylic acids from alkenes

MZ Deng, DA Lu, WH Xu

文献索引:Deng, Min-Zhi; Lu, Ding-An; Xu, Wei-Hua Journal of the Chemical Society, Chemical Communications, 1985 , # 21 p. 1478 - 1479

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被引用次数: 1

摘要

It has been shown that trialkylvinylborate can react with electrophiles such as iodine,l epoxide,2 and aldehyde in a similar manner to trialkylalkynylborate.3 Recently, we have carried out the carboxylation of trialkylalkynylborate yielding a stereospecific a,P-unsaturated acid in high yield.4 Here, we report the result of the reaction between trialkylvinylborate and carbon dioxide. Under pressure, chloromagnesium trialkylvinylborate re-