Tetrahedron

Reaction of 2, 6-dimethyl-4-methoxybenzaldehyde with methylmagnesium iodide and some properties of the reaction products

T Kamikawa, M Nakatani, T Kubota

文献索引：Kamikawa,T. et al. Tetrahedron, 1968 , vol. 24, p. 2091 - 2100

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被引用次数: 6

摘要

Treatment of 2, 6-dimethyl-4-methoxybenzaldehyde with MeMgI afforded two isomeric ethers,(1A and 1B), instead of the desired 1-(2, 6-dimethyl-4-methoxyphenyl) ethanol. The NMR spectra of the high-melting isomer (1B) showed the presence of hindered rotation of aromatic Me groups. The reactions and properties of these ethers and other related ethers were examined.