Biofunctional Silicon Nanoparticles by Means of Thiol??Ene Click Chemistry

L Ruizendaal, SP Pujari, V Gevaerts…

文献索引：Ruizendaal, Loes; Pujari, Sidharam P.; Gevaerts, Veronique; Paulusse, Jos M. J.; Zuilhof, Han Chemistry - An Asian Journal, 2011 , vol. 6, # 10 p. 2776 - 2786

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被引用次数: 45

摘要

Abstract The preparation and characterization of butylene-terminated silicon nanoparticles (SiNPs) and their functionalization using thiol-ene chemistry is described, as well as the coupling of DNA strands. Bromide-terminated SiNPs were prepared by means of the oxidation of magnesium silicide and functionalized with butylene chains through treatment with the corresponding Grignard reagent. The successful coupling was confirmed by NMR ...