Syntheses and interfacial behaviour of neoglycolipid analogues of glycosyl ceramides

…, MN Bouchu, A Girard-Egrot, P Boullanger

文献索引：Lafont, Dominique; Bouchu, Marie-Noelle; Girard-Egrot, Agnes; Boullanger, Paul Carbohydrate Research, 2001 , vol. 336, # 3 p. 181 - 194

全文：HTML全文

被引用次数: 33

摘要

Four glycosyl ceramides analogues having d-galactose or 2-acetamido-2-deoxy-d-glucose moieties linked to enantiomeric lipids have been synthesised to study their interfacial behaviour at the air∣ water interface. The lipid chains were prepared in two steps by opening 1, 2-epoxyhexadecane using Jacobsen kinetic hydrolytic resolution (KHR) followed by an azidosilylation reaction of the diol so obtained. Glycosylation reactions were ...