Inorganica Chimica Acta

C Si bond cleavage of trihalomethyltrimethylsilane by alkoxo-and aryloxogold or-copper complexes

Y Usui, J Noma, M Hirano, S Komiya

文献索引：Usui, Yoko; Noma, Junko; Hirano, Masafumi; Komiya, Sanshiro Inorganica Chimica Acta, 2000 , vol. 309, # 1-2 p. 151 - 154

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被引用次数: 30

摘要

The C Si bond cleavage of trihalomethyltrimethylsilane Me3SiCX3 (X= F, Cl) proceeds smoothly by alkoxo-and aryloxogold (I or III) or-copper (I) complexes Au (OR) L (OR= OCH (CF3) 2, OPh), L= PCy3, PPh3, PMe2Ph, PMe3), cis-AuMe2 (OPh) L (L= PMePh2, PEt3, PMe2Ph, PMe3), Cu (OR)(PPh3) 3 (OR= OCH (CF3) 2, OPh) to give trihalomethylgold or- copper complexes Au (CX3) L, cis-AuMe2 (CF3) L, or Cu (CF3) L3 with liberation of the ...