Trinuclear Copper (I)??bipyridine Triskelion: Template/Bascule Control of Coordination Complex Stereochemistry in a Trefoil Knot Precursor

…, M Benaglia, S Toyota, K Hardcastle…

文献索引：Woods, Craig R.; Benaglia, Maurizio; Toyota, Shinji; Hardcastle, Kenneth; Siegel, Jay S. Angewandte Chemie - International Edition, 2001 , vol. 40, # 4 p. 749 - 751

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被引用次数: 51

摘要

Abstract The construction of molecules such as knots and links can be facilitated by using metal–ligand coordination complexes as template structures; however, the control of the stereochemistry by cooperative steric interactions among metal–ligand sites remains a challenge. A simple, but general, cantilever control mechanism is demonstrated here through the stereoselective synthesis of a trinuclear copper (I)-bipyridine triskelion (see ...