A series of photoactive conjugated low band-gap copolymer (CPSB) and terpolyemrs (TPSBCz-n, n= 1 to 4) based on N-alkyl carbazole, 4, 4′-dialkyl dithienosilole, and bezothiadiazole were synthesized. The copolymer and terpolymers were built with the fraction of the carbazole unit varied for 0, 2.5, 5, 10 and 25 mol%. Among the mixtures, the composition of 25 wt% of terpolymer bearing 10 mol.% of the carbazole unit, TPSBCz-3, ...