Structures and properties of 6-aryl substituted tris (2-pyridylmethyl) amine transition metal complexes

Z He, DC Craig, SB Colbran

文献索引：He, Zhicong; Craig, Donald C.; Colbran, Stephen B. Journal of the Chemical Society, Dalton Transactions, 2002 , # 22 p. 4224 - 4235

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被引用次数: 28

摘要

A series of metal (II) complexes of [6-(2′, 5′-dimethoxyphenyl)-2-pyridylmethyl] bis (2- pyridylmethyl) amine (L) have been prepared. X-Ray crystal structures have been determined for L and its metal (II) chloride complexes for Mn, Fe, Co, Ni, Cu and Zn and the results compared. The preparation and crystal structure of the unusual carbonato-bridged copper-tetramer [Cu4 (L) 4 (CO3) 2][BF4] 4· 5.2 H2O is also described. The solution-state ...