Tetrahedron

Vinyl MIDA boronate: a readily accessible and highly versatile building block for small molecule synthesis

BE Uno, EP Gillis, MD Burke

文献索引：Uno, Brice E.; Gillis, Eric P.; Burke, Martin D. Tetrahedron, 2009 , vol. 65, # 16 p. 3130 - 3138

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被引用次数: 74

摘要

Iterative cross-coupling represents a potentially general approach for the simple, efficient, and flexible construction of natural products, pharmaceuticals, and materials. N- Methyliminodiacetic acid (MIDA) boronates represent a promising platform for the development of this type of synthesis strategy. This report describes the discovery that vinyl MIDA boronate (1) is an air-and chromatographically stable compound that can be ...