Energy??Minimized Structures and Calculated and Experimental Isomer distributions in the hexaamine??cobalt (III) system [Co (L) 2] 3+ with the chiral facially?? …
Abstract Butane-1, 2, 4-triamine (trab) is the smallest tridentate aliphatic unsubstituted chiral triamine. With optically pure trab, there are three, with racemic trab five isomers of [Co (trab) 2] 3+, One of the five isomers is centrosymmetrical, the others are chiral. For one of the isomers, there are four possible conformations (all combinations of chair and skew boat conformations for the chelate six ring of each ligand), for the others there exist only three ...
