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The Journal of Physical Chemistry A

2H NMR Investigations of the Hexadecane/Urea Inclusion Compound

J Schmider, K Müller

文献索引:Schmider, Judith; Mueller, Klaus Journal of Physical Chemistry A, 1998 , vol. 102, # 7 p. 1181 - 1193

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被引用次数: 42

摘要

The molecular behavior of selectively deuterated n-hexadecane in the urea inclusion compound is studied between 100 and 290 K by means of dynamic 2H NMR spectroscopy employing line shape studies and spin-spin and spin-lattice relaxation experiments. Particular emphasis is given to the changes of the guest molecule behavior close to a solid- solid phase transition occurring at lower temperatures which is accompanied by a ...