Iron complexes bearing iminopyridine and aminopyridine ligands as catalysts for atom transfer radical polymerisation

…, RK O'Reilly, DF Wass, AJP White, DJ Williams

文献索引：Gibson, Vernon C.; O'Reilly, Rachel K.; Wass, Duncan F.; White, Andrew J.P.; Williams, David J. Dalton Transactions, 2003 , # 14 p. 2824 - 2830

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被引用次数: 44

摘要

A series of iron (II) complexes bearing iminopyridine and aminopyridine ligands with N-alkyl and N-aryl substituents has been synthesised. X-Ray crystal structures of n-propyl-and 2, 6- diisopropylphenyl-iminopyridine derivatives reveal dinuclear structures with halide bridges; a derivative carrying a cyclododecyl imine substituent and an α-methylpyridine unit is mononuclear. In studies of their atom transfer radical polymerisation behaviour, the ...