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The Addition of N-Bromomorpholine to Benzalacetophenone

PL Southwick, WL Walsh

文献索引:Southwick; Walsh Journal of the American Chemical Society, 1955 , vol. 77, p. 405,407

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被引用次数: 6

摘要

The possibility of adding an N-haloamine to an unsaturated compound has been demonstrated; direct addition of the elements of N-bromomorpholine to trans- benzalacetophenone has produced a new form of a-bromo-B-morpholinobenzylaceto- phenone, the diastereoisomer of the previously known form. Hydrolysis and methanolysis of the new isomer proceeded readily, yielding, respectively, a-morpholino-B- ...