The Journal of Physical Chemistry A

The Reinvestigation of the Kinetics of the Metathesis Reactions t-C4H9•+ HBr (HI)→ i-C4H10+ Br•(I•) and of the t-C4H9• Free Radical Thermochemistry

N Leplat, MJ Rossi

文献索引：Mueller-Markgraf, Wolfgang; Rossi, Michel J.; Golden, David M. Journal of the American Chemical Society, 1989 , vol. 111, # 3 p. 956 - 962

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被引用次数: 5

摘要

A reinvestigation of the absolute rate constant of the metathesis reactions t-C4H9•+ HBr→ i- C4H10+ Br•(1) and t-C4H9•+ HI→ i-C4H10+ I•(2) was performed thanks to a recently developed apparatus consisting of a Knudsen reactor coupled to detection based on single-