Comparison of reactivities of 1-and 4-oxotetrahydrocarbazoles in reactions with nucleophilic and electrophilic reagents

…, VI Levina, KI Kobrakov, NB Grigor'ev…

文献索引：Kukushkin; Ivanov; Alekseeva; Levina; Kobrakov; Grigor'ev; Granika Russian Chemical Bulletin, 2005 , vol. 54, # 8 p. 1887 - 1891

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被引用次数: 5

摘要

Abstract The half-wave potentials of polarographic reduction of the carbonyl group in unsubstituted and N-methyl-and N-phenylsulfonyl-substituted 1-and 4- oxotetrahydrocarbazoles and their reactivities in reactions with nucleophilic (NaBH 4, malonodinitrile, and cyanoacetamide) and electrophilic (DMF dimethyl acetal) reagents were compared. 4-Oxotetrahydrocarbazoles are much less reactive than 1- ...