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Experiments in the 1, 2-Di-(γ-pyridyl)-ethane Series1

ED Bergmann, FE Crane Jr…

文献索引:Bergmann Journal of the American Chemical Society, 1952 , vol. 74, p. 828

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被引用次数: 26

摘要

1, 2-Di-(y-pyridy1)-ethane and its methiodide are readily oxidized to the corresponding ethylene derivatives. The two base3 form mixed crystals, as do their salts. The ethylene absorbs strongly at 295 mp, where stilbene has its absorption. A pronounced hathochromic shift occurs on methiodation; the bismethiodide of the ethylene absorbs at 315 mp, approximately where diphenylbutadiene absorbs. Both methiodides show a much ...