Journal of Organometallic Chemistry

Dissoziative ionisierung von 2-trimethylsilyl-1-phenoxyethan. Nachweis des nicht-klassischen ethylen-trimethylsilanium-ions in der gasphase

B Ciommer, H Schwarz

文献索引：Ciommer, Bernhard; Schwarz, Helmut Journal of Organometallic Chemistry, 1983 , vol. 244, # 4 p. 319 - 328

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被引用次数: 11

摘要

Abstract The mass spectrometric investigation of specifically deuterium and 13 C labelled 2- trimethylsilyl-l-phenoxyethanes proves that the dissociative ionization of β-silyl-substituted ethane derivatives (loss of PhO⊎; p-CH 3 C 6 H 4 O⊎; and C 4 H⊎ 9 from PhOCH 2 CH 2 SiMe 3, p-MeC 6 H 4 OCH 2 CH 2 SiMe 3 and CH 3 CH 2 CH (CH 3) CH 2-CH 2 SiMe 3, respectively) yields the non-classical bridge ethylene trimethylsilanium ion and not the ...