Dipalladium (I) Terphenyl Diphosphine Complexes as Models for Two-Site Adsorption and Activation of Organic Molecules
S Lin, DE Herbert, A Velian, MW Day…
文献索引：Lin, Sibo; Herbert, David E.; Velian, Alexandra; Day, Michael W.; Agapie, Theodor Journal of the American Chemical Society, 2013 , vol. 135, # 42 p. 15830 - 15840
A para-terphenyl diphosphine was employed to support a dipalladium (I) moiety. Unlike previously reported dipalladium (I) species, the present system provides a single molecular hemisphere for binding of ligands across two metal centers, enabling the characterization and comparison of the binding of a wide variety of saturated and unsaturated organic molecules. The dipalladium (I) terphenyl diphosphine toluene-capped complex was ...
