Journal of Physical Chemistry

Electronic branching in reactions of calcium (3P, 1D) and magnesium (3P) with fluorine, chlorine, and bromine: experiments and global model

A Kowalski, M Menzinger

文献索引：Kowalski, Andrzej; Menzinger, Michael Journal of Physical Chemistry, 1990 , vol. 94, p. 1899 - 1906

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被引用次数: 20

摘要

Results are reported from a systematic study of electronic branching in the reactions of metastable alkaline earth atoms with halogen molecules. They form chemiluminescent (CL), ionic (CI), and" dark" products. It was found that (1) the CI yields are of the order of 1% in all systems studied;(2) the CL channels are characterized by high yields (5-35%) in the Ca (3P) reactions and by low yields, of the order of 1%, for the Mg (3P) systems;(3) beam ...