Reactions of fluorobenzene tricarbonylchromium complexes with anions from Schiff bases of α-amino esters; enantioselective synthesis of α-aryl amino acids
M Chaari, A Jenhi, JP Lavergne, P Viallefont
文献索引：Chaari, Mohamed; Jenhi, Aicha; Lavergne, Jean-Pierre; Viallefont, Philippe Tetrahedron, 1991 , vol. 47, # 26 p. 4619 - 4630
We report here a convenient synthesis of α-substituted aryl amino acids via the addition of α- amino esters to fluorobenzene tricarbonylchromium complexes. Optically pure α-aryl amino acids have been prepared by enantioselective substitution of fluorobenzene complexes using Schiff bases of L-alanine, leucine and valine methyl esters and (1R, 2R, 5R)-2- hydroxypinan-3-one.
