Tetrahedron

Substitutions nucleophiles d'olefines fluorees—I

J Normant, R Sauvetre, J Villieras

文献索引：Normant,J. et al. Tetrahedron, 1975 , vol. 31, p. 891 - 896

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被引用次数: 10

摘要

The nucleophilic substitution of fluorinated alkenes of type C6H5 CF CFCl proceeds by addition-elimination. The addition occurs on the carbon atom bearing the chlorine atom. The stereospecificity depends on steric hindrance in the transition state of the elimination step. The stereochemical outcome is retention of configuration.