Phosphinite Ligand Effects in Palladium (II)??Catalysed Cycloisomerisation of 1, 6??Dienes: Bicyclo [3.2. 0] heptanyl Diphosphinite (B [3.2. 0] DPO) Ligands Exhibit …

…, S Tommasi, JM Lynam, M Bandini…

文献索引：Fairlamb, Ian J. S.; Grant, Stephanie; Tommasi, Simona; Lynam, Jason M.; Bandini, Marco; Hao, Dong; Zhenyang, Lin; Whitwood, Adrian C. Advanced Synthesis and Catalysis, 2006 , vol. 348, # 16-17 p. 2515 - 2530

全文：HTML全文

被引用次数: 23

摘要

Abstract Changes in bidentate ligand structure significantly affect catalytic activity in mono- cationic Pd (II)-catalysed 1, 6-diene cycloisomerisation processes to give cyclopentene products. A bicyclo [3.2. 0] heptanyl diphosphinite ligand (B [3.2. 0] DPO, 3) is the first phosphorus-based bidentate ligand capable of promoting regioselective 1, 6-diene cycloisomerisation. Trace quantities of water are essential for catalytic activity, as is the ...