System vanadium alkoxy compound-tert-butyl hydroperoxide-oxidant of hydrocarbon CH bonds

…, MV Gulenova, AN Tishkina, VK Cherkasov

文献索引：Stepovik; Gulenova; Tishkina; Cherkasov Russian Journal of General Chemistry, 2007 , vol. 77, # 7 p. 1254 - 1262

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被引用次数: 7

摘要

Abstract Vanadium alkoxy compounds [(t-BuO) 4 V,(t-BuO) 3 VO] react with tert-butyl hydroperoxide (C 6 H 6, 20° C) to liberate oxygen, partly in the singlet form, and to form alkoxyl and peroxyl radicals via the intermediacy of vanadium peroxides and trioxide. These systems are capable of oxidizing hydrocarbon CH bonds. The process is radical in nature and involves formation of carbon-centered radicals and their reaction with oxygen ...