Carbohydrate research

A method for obtaining equilibrium tautomeric mixtures of reducing sugars via glycosylamines using nonaqueous media

SS Allavudeen, B Kuberan, D Loganathan

文献索引：Allavudeen, Sikkander Sulthan; Kuberan, Balagurunathan; Loganathan, Duraikkannu Carbohydrate Research, 2002 , vol. 337, # 10 p. 965 - 968

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被引用次数: 10

摘要

Equilibrium tautomeric mixtures of several mono-and disaccharides are obtained in anhydrous form, without the use of water, by reacting the commercially available reducing sugars with ammonia gas in dry methanol, followed by the concentration of the resultant solution to dryness. Mutarotation and hydrolysis of the initially formed glycosylamine in the resultant medium account for the transformation. Equilibrium anomeric mixtures enriched ...