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Tetrahedron letters

An efficient synthesis of conjugated nitro-olefins using ceric ammonium nitrate

AS Rao, PV Srinivas, KS Babu, JM Rao

文献索引:Sridhar Rao; Srinivas; Suresh Babu; Madhusudana Rao Tetrahedron Letters, 2005 , vol. 46, # 47 p. 8141 - 8143

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被引用次数: 21

摘要

The nitro group is a powerful electron-withdrawing substituent and this property dominates the chemistry of all molecules containing this functional group. Nitroalkenes are powerful dienophiles in the Diels–Alder reaction. 1 The versatility of the nitro group makes possible its transformations into many compounds with diverse functionalities. Removal of a nitro group leading to the formation of carbonyl compounds in the classical Nef reaction is well known. 1 Significant biological ...