High fidelity kinetic self-sorting in multi-component systems based on guests with multiple binding epitopes

P Mukhopadhyay, PY Zavalij…

文献索引：Mukhopadhyay, Pritam; Zavalij, Peter Y.; Isaacs, Lyle Journal of the American Chemical Society, 2006 , vol. 128, # 43 p. 14093 - 14102

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被引用次数: 132

摘要

The molecular recognition platforms of natural systems often possess multiple binding epitopes, each of which has programmed functional consequences. We report the dynamic behavior of a system comprising CB [6], CB [7], and guests cyclohexanediammonium (1) and adamantanealkylammonium (2) that we refer to as a two-faced guest because it contains two distinct binding epitopes. We find that the presence of the two-faced guest ...