Inorganic Chemistry

Kinetics and mechanism of trimethylamine-haloborane hydrolysis

JR Lowe, SS Uppal, C Weidig, HC Kelly

文献索引：Lowe, J. R.; Uppal, S. S.; Weidig, C.; Kelly, H. C. Inorganic Chemistry, 1970 , vol. 9, p. 1423 - 1427

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被引用次数: 20

摘要

The rates of solvolysis of trimethylamine-monohaloboranes in aqueous dioxane at 25'increase in the series (CHa) &BHsCI<(CH8) 8NBHiBr<(CHs) JTBH21. The diiodoborane adduct reacts more slowly than the monoiodo compound but faster than trimethylamine- borane. Only a very slight retardation in rate is observed on substitution of deuterium for hydrogen on boron in the diiodo derivative (kH/kD= 1.1); however, a noticeable solvent ...