Tetrahedron

Stannyl ester cyclizations

GA Kraus, K Landgrebe

文献索引：Kraus, George A.; Landgrebe, Kevin Tetrahedron, 1985 , vol. 41, # 19 p. 4039 - 4046

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被引用次数: 31

摘要

Alpha halo stannyl esters react with alkenes to afford lactones. The reaction is catalyzed by AIBN. The reaction proceeds best with electron rich alkenes. The mechanistic aspects of this novel reaction are discussed. This reaction can also be conducted intramolecularly to produce bicyclic lactones. An approach to the lignan system is presented.