Carbohydrate Research

Aminoglycosides of D-pinitol. The 3-amino-3-deoxy-α-D-glucopyranoside, THE 3-acetamidino analog, and the 3, 6-dideoxy-3, 6-epimino-α-D-glucopyranoside

JY Tang, L Anderson

文献索引：Tang,J.-Y.; Anderson,L. Carbohydrate Research, 1977 , vol. 59, p. 319 - 331

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被引用次数: 1

摘要

Abstract 3-Azido-2, 4, 6-tri-O-benzyl-3-deoxy-α-D-glucopyranosyl chloride (7), prepared conventionally from the azido precursor 2, was coupled with “diisopropylidene-D-pinitol”(8) to give the α-D-glucoside 9 in good yield, together with some β anomer. Removal of the O- benzyl groups from 9 and reduction of the azido group to− NH 2 were accomplished simultaneously. Further deprotection yielded 11, a 3-amino-3-deoxy-α-D-glucoside of D- ...