New organotin (IV)-phosphoramidate complexes: Breaking of the PO⋯ HN hydrogen bonds and its influence on the molecular packing

…, KH Pannell, MR Chaijan, H Eshtiagh-Hosseini

文献索引：Metta-Magana, Alejandro J.; Pourayoubi, Mehrdad; Pannell, Keith H.; Rostami Chaijan, Mahnaz; Eshtiagh-Hosseini, Hossein Journal of Molecular Structure, 2012 , vol. 1014, p. 38 - 46

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被引用次数: 6

摘要

Phosphoryl donor (PO) ligands (tBuNH) 3PO (1),(C6H5CH2NH) 3PO (2) and (4-NO2– C6H4C (O) NH)(OC4H8N) 2PO (3) were used for the preparation of new organotin (IV) complexes Cl2Me2Sn (PO) 2 (4–6). The environment at the nitrogen atom in the phosphoramide ligand is almost planar and it does not take part in hydrogen bonding as an acceptor in complexes 4–6, reflecting its low Lewis base character, and the Sn atom is ...