Conformational analysis of 5-substituted 1, 3-dioxanes. 2. Phenylthio and cyclohexylthio groups and their sulfinyl and sulfonyl derivatives

E Juaristi, B Gordillo, M Sabahi…

文献索引：Juaristi, Eusebio; Gordillo, Barbara; Sabahi, Mahmood; Glass, Richard S. Journal of Organic Chemistry, 1990 , vol. 55, # 1 p. 33 - 38

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被引用次数: 5

摘要

The positions of equilibrium, established by acid catalysis, between diastereomeric cis-and trum-5-(phenylthio)-(7), 5-(phenylsulfinyl)-(8), 5-(phenylsulfonyl)-(9), 5-(cyclohexy1thio)-(lo), 5-(cyclohexylsulfinyl)-(1 l), and 5-(cyclohexylsulfonyl)-2-tert-butyl-1, 3-dioxanes (12) are reported and compared with published data for the 5-(methy1thio)-(l), 5-(methylsulfinyl)-(2), 5-(methylsulfonyl)-(3), 5-(tert-butylthio)-(4), 5-(tert-butylsulfinyl)-(5), and 5-(tert- ...