Therefore, the syntheses of biologically important thiocarbamates have received considerable attention, and there are few reports for the synthesis of dithiocarbamate derivatives in the literature. Among them, reaction of amine with costly and toxic reagents, such as thiophosgene and isothiocyanate, is reported as a general route. [8] A one-pot reaction of amines with carbonyl sulfide and Michael acceptor in organic solvent has also been developed. [9] However, ...
