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Perfluoropropyl-substituted Thia-, Oxa-and Aza-dicarboxylic Esters1, 2

ET McBee, CW Roberts, G Wilson Jr

文献索引:McBee et al. Journal of the American Chemical Society, 1958 , vol. 80, p. 1719

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被引用次数: 0

摘要

The reactions of hydrogen bromide, ethanol, butylamine and methylamine with ethyl 4, 4, 5, 5, 6, 6, 6-heptafluoro-2-hexeno-ate gave ethyl 3-bromo-, 3-ethoxy, 3-butylamino-and 3- methylamino-4, 4,~, j, B, 6,~, 6-heptafluorol~ e~ anoates, respectively Additions of ethyl glycinate and ethyl mercaptoacetate to the same unsaturated ester gave diethyl 4- perfluoropropyl-3-azahexanedioate and diethyl 4-perfluoropropyl-3-thiahexanetiioate; the ...