Equilibrium acidities of superacids

…, I Kaljurand, IA Koppel, RY Garlyauskayte…

文献索引：Kuett, Agnes; Rodima, Toomas; Saame, Jaan; Raamat, Elin; Maeemets, Vahur; Kaljurand, Ivari; Koppel, Ilmar A.; Garlyauskayte, Romute Yu.; Yagupolskii, Yurii L.; Yagupolskii, Lev M.; Bernhardt, Eduard; Willner, Helge; Leito, Ivo Journal of Organic Chemistry, 2011 , vol. 76, # 2 p. 391 - 395

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被引用次数: 115

摘要

In this paper, we report the most comprehensive equilibrium superacidity scale that is available to date. Contrary to most of the past works, this scale is set up in a medium of constant composition and the obtained acidity values characterize the acidities of molecules rather than acidities of media. The current scale is thus complementary to the well-known H 0 scale in the information that it provides. The solvent used is 1, 2-dichloroethane (DCE). ...