The Journal of Organic Chemistry

Alkyllithium Compounds and Nonconjugated Olefins. The Nature of a Norbornyllithium Compound

JE Mulvaney, ZG Gardlund

文献索引：Mulvaney,J.E.; Gardlund,Z.G. Journal of Organic Chemistry, 1965 , vol. 30, p. 917 - 920

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被引用次数: 31

摘要

In diethyl ether solution at-40" t-butyllithium and norbornene after carbonation give 4, 4dimethylpentanoic acid, a product arising from addition of t-butyllithium to liberated ethylene from the solvent. Under the same conditions t-butyllithium adds to vinyltrimethylsilane yielding, after carbonation, 2-trimethylsilyl-4.4-dimethylpentanoic acid (VII). The nmr spectra of the products from hydrolysis or carbonation show that the product ...