Apparently regular octahedral coordination of Ag (II) in IF6 [Ag (SbF6) 3]

…, I Arčon, N Zabukovec Logar, V Kaučič

文献索引：Mazej, Zoran; Goreshnik, Evgeny; Arcon, Iztok; Logar, Natasa Zabukovec; Kaucic, Venceslav Zeitschrift fur Anorganische und Allgemeine Chemie, 2010 , vol. 636, # 1 p. 224 - 229

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被引用次数: 2

摘要

Abstract The crystal structure of IF 6 [Ag (SbF 6) 3] has been determined by X-ray single crystal and X-ray powder diffraction analysis. The structure consists from [Ag (SbF 6) 3]– chains and [IF 6]+ cations placed between them. Ag 2+ is found in regular octahedral coordination of six fluorine atoms [Ag–F= 6× 2.170 (12) Å]. EXAFS analysis of Jahn–Teller distortions in IF 6 [Ag (SbF 6) 3] shows that Ag 2+ surrounding is elongated octahedral at ...