Macromolecules

Aqueous poly (arylacetylene) dispersions

J Huber, S Mecking

文献索引：Huber, Johannes; Mecking, Stefan Macromolecules, 2010 , vol. 43, # 21 p. 8718 - 8723

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被引用次数: 24

摘要

Aqueous poly (phenylacetylene) dispersions were obtained by catalytic polymerization in emulsion with a phosphine-modified Pd (II) catalyst. A range of mono-and bidentate phosphines were screened. A t Bu2P (CH2) 3P t Bu2-modified catalyst exhibits very high rates up to 2× 105 TO h− 1 (TO= moles of monomer converted per mole of metal present in the reaction mixture) in the preparation of colloidally stable poly (phenylacetylene) ...