Tetrahedron letters

Synthesis of novel β-functionalized α-oximinoketones via hetero-Michael addition of alcohols and mercaptans to enones

P Bernal, J Tamariz

文献索引：Bernal, Pablo; Tamariz, Joaquin Tetrahedron Letters, 2006 , vol. 47, # 17 p. 2905 - 2909

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被引用次数: 17

摘要

A new methodology has been developed for the preparation of β-alkoxy and β-sulfenyl ketones by hetero-Michael addition of the corresponding alcohols and thiols to enones under acidic and basic conditions. The direct conversion of enones into β-alkoxy and β- sulfenyl α-oximinoketones was also described.