Olefin epoxidation in solventless conditions and apolar media catalysed by specialised oxodiperoxomolybdenum complexes

M Herbert, F Montilla, A Galindo

文献索引：Herbert, Matthew; Montilla, Francisco; Galindo, Agustin Journal of Molecular Catalysis A: Chemical, 2011 , vol. 338, # 1-2 p. 111 - 120

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被引用次数: 26

摘要

The epoxidation of olefin substrates, in both apolar organic media and under solventless conditions, with aqueous hydrogen peroxide and catalysed by molybdenum complexes has been investigated. The catalysts compounds employed were the oxodiperoxomolybdenum complexes of several pyridine, 2, 2′-bipyridine and pyrazole ligands with apolar functions (alkyl chains, alkyl-trimethylsilyl groups and polydimethylsiloxanyl polymer), which ...