A new strategy for the enantioselective synthesis of carba-prostacyclin analogues based on organocopper conjugate addition to a bicyclic azoene and its application …
M van Bergen, HJ Gais
文献索引：Journal of the American Chemical Society, , vol. 124, # 16 p. 4321 - 4328
![(3a'R,6a'S)-5,5-dimethyltetrahydro-1'H-spiro[1,3-dioxane-2,2'-pentalen]-5'(3'H)-one结构式](https://image.chemsrc.com/caspic/451/112755-94-9.png)
![(-)-(3'aS-cis)-N-[3',3'a,4',6'a-tetrahydro-5,5-dimethylspiro[1,3-dioxane-2,2'(1'H)-pentalen-5'-yl]]-N'-(p-toluenesulfonyl)diazene结构式](https://image.chemsrc.com/caspic/094/873949-36-1.png)
![(+)-(3'aS-cis)-trimethyl[(3',3'a,4',6'a-tetrahydro-5,5-dimethylspiro[1,3-dioxane-2,2'(1H)-pentalen]-5'-yl)oxy]silane结构式](https://image.chemsrc.com/caspic/204/128888-91-5.png)
![(-)-(3'aS,4'R,6'aR)-[4'-chloro-1',6'a,6',3'a-tetrahydro-5,5-dimethylspiro[1,3-dioxane-2,2'(1'H)-pentalen]]-5'-one结构式](https://image.chemsrc.com/caspic/396/431041-18-8.png)