Reductive Azidation of Carbonyl Compounds via Tosylhydrazone Intermediates Using Sodium Azide

J Barluenga, M Tomás??Gamasa…

文献索引：Barluenga, Jose; Tomas-Gamasa, Maria; Valdes, Carlos Angewandte Chemie - International Edition, 2012 , vol. 51, # 24 p. 5950 - 5952

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被引用次数: 33

摘要

The azide functionality has drawn considerable interest since the late 19th century as a result of its versatile reactivity. Organic azides have found wide application in organic synthesis as precursors of fundamental nitrogen functionalities [1, 2] as well as of nitrogen- containing heterocycles. Moreover, the development of the Cu-catalyzed azide–alkyne cycloaddition,[3, 4] the most representative example of click chemistry,[5] has established ...