Dalton Transactions

Strong reducing agents containing dimolybdenum Mo 2 4+ units and their oxidized cations with Mo 2 5+/6+ cores stabilized by bicyclic guanidinate anions with a …

FA Cotton, CA Murillo, X Wang, CC Wilkinson

文献索引：Cotton, F. Albert; Murillo, Carlos A.; Wang, Xiaoping; Wilkinson, Chad C. Dalton Transactions, 2006 , # 38 p. 4623 - 4631

全文：HTML全文

被引用次数: 21

摘要

The syntheses of two analogues of the bicyclic guanidinate ligand hpp (hpp= the anion of the guanidine-type compound 1, 3, 4, 6, 7, 8-hexahydro-2H-pyrimido [1, 2a] pyrimidine) which contain two fused rings are reported. Each compound contains one seven-membered ring while the other is either a five (Htbd) or a six (Htbu) membered ring. In THF/Bu4NPF6, the dimolybdenum compounds Mo2 (tbd) 4 and Mo2 (tbu) 4 are easily oxidized and they ...