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Organic letters

Absolute rate constants for water protonation of 1-(3-benzoylphenyl) alkyl carbanions

G Cosa, L Llauger, JC Scaiano, MA Miranda

文献索引:Cosa, Gonzalo; Llauger, Laura; Scaiano; Miranda, Miguel A Organic letters, 2002 , vol. 4, # 18 p. 3083 - 3085

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被引用次数: 23

摘要

Efficient photodecarboxylation of (3-benzoylphenyl) alkanoic acids with formation of carbanions has enabled the determination of their protonation rate constants in water; the values obtained show that the reactivity toward protonation is determined by the size of the alkyl groups attached to the carbanion center.